No. The only "older" woman was Maymoonah (if I recall her name correctly). She was his first wife after Khadijah , married her not even a year before Aishah, and she even gave up her day to Aishah in fear that Mo would divorce her. She was old and haggard, described in the hadeeth. As for his other wives, for example Zaynab, Umm Salamah or Safia etc they were all young and known for their beauty (all described in the hadeeth). They had many suitors before Mo asked for them in marriage.
Talk about "older", "widows", and "divorcees" is all bullshit. Believe me, Mo married no old ugly women. Except Maymoonah, miskeenah, but she didn't even spend any time with her "husband". Try to recall how many times she's mentioned taking part in the interaction in the household of Mo. Basically never....
Oh, alright, I will replace the word "older" with the word "used" women, this is what I meant by old lol, coz once you have been de-flowered by these guys, and bared a few children, despite your age, you look like an old maid anyway and considered ollld lol..